ACS Technology
Providing 
Pathogen Control and
Extend Shelf-Life
with 
"ACS"
Acidic Calcium Sulfate
" USDA & FDA Approved "   

 

 

 

 

 

 

 

 

Your Subtitle text

Pathogen Control Treatments

 Preventing Salmonella in Chlorinated Water Treatment       

 Fruit & Vegetable Treatment

 

ACS Technology Inc., aka Mionix CO, is a diversified, platform based biotechnology company, dedicated to providing innovative and proprietary technology, products, and solutions for quality assurance in such diverse industries as food processing, pet food, poultry pathogen treatment, agribusiness, facilities sanitation, and fish processing industry, to enhance the quality of products worldwide.

This unique patented technology --  is a multi-industry and multi-application platform called Acidic Calcium Sulfate (ACS) also known as acidified calcium sulfate, is a foundation for a family of formulations of SafepHix ® & SafepHix ® Safe2O ®brand products, and  " FDA and USDA  Approved ".   ACS has successfully enabled ACS Technology products to effectively inhibit microbial growth and substantially reduced pathogen contamination levels, thus making ACS Technology, a leader in Food Safety.

ACS Technology agribusiness line of value added products are focused on providing food animal growers with products that help reduce and control bacterial contaminates.
 
These products include " FreshFlo ", &  " FreshFlo 100 ",  our premium Poulty / animal drinking water acidulant, " pHixr "  &" pHixr 100 ", our market leading Poultry Processing Water Acidulant, and " FrespHix " or "pHresh pHix ",  a commercial 
Fruit & Vegetable processing water acidulant to optimize food pathogen control with chlorinated water.  Provides proper ORP for maximum  effectiveness for killing bacteria.

By adding ACS Technology's Safe-pHix brand "pHixr 100" to your chlorinated processing water, your can improve the ORP-Oxidation Reduction Potential, and increase antimicrobial efficacy or antimicrobial effectiveness.  Can be used poultry water operations and on whole vegetables.  

This eliminated contamination of water and pollution of groundwater. "pHixr 100" is used for prevention of e coli,and other food borned bacteria. ie: Treatment for Salmonella, Prevention Salmonella Campylobacter, without loss of taste, or loss of smell of your quality products.


                                           " ACS " Product List

Product

MSDS

Use


FreshFlo 100®
&

FreshFlo ®

 

FreshFlo 100

Poultry Drinking Water Acidulant, USDA Approved.
Focused on providing food animal growers with a reduction and control of bacterial contaminates, reducing mortality rates and improving yields. 

pHixr 100®

PWT Liquid

Poultry Water Treatment

pHixr 100
 

Processing water treatment acidulant for animals &  PWT - Poultry Water Treatment for
slaughter operations and applications, and
Fish processing operations

Controls Salmonella, Campylobacter, E.coli,
 

 

 

 

 

 

 

pHreshpHix®
&
  FreshpHix
  

FreshpHix

Fresh Fruit and Vegetable processing water acidulant for controlling Salmonella, Campylobacter, E.coli.        USDA Approved.

 RTE 01® 
    Listeria m    Control

RTE 01


FDA Approved for Ready to Eat Meat products. Listeria m & other food pathogen control for: turkey, frankfurters, beef jerky, sausage products, deli meats, roast chicken, pre-packaged fruits, vegetables and salads, and other foods. Hand dipped or auto sprayed onto product.
 

AFT 100®


Animal Feed Treatment for pathogen control. 

AFT 100
                        

ACS 100®
 

Acidic Calcium Sulfate®

 ACS 100®

 Kosher USDA Approved Food Ingredient acidulant for  pH control of food products.
NO Taste Issues
EXTENDS Shelf Life
SAFE to use & COST Effective.

 

 

 

 

   What can  ACS Technology® products do?

  • Help make food safer by preventing the attachment and re-attachment of E.coli O157:H7, Listeria monocytogenes, Salmonella, Campylobacter and other pathogens. 
  • Significantly reduce or eliminate mold.
  • Helps food last longer by reducing spoilage or decay bacteria.
    Food can last longer resulting in reduced losses from spoilage, producing better financial returns and providing an increase in market distribution opportunities.
  • Provide reduced "D-value", the relationship between time and temperature required to cook food to ensure harmful bacteria are killed.* 
  • Temperature abuse protection.*
    * "D" Value and temperature abuse protection are ONLY available in foods that contains ACS Technology®
  • Aid in making food more nutritious by calcium enrichment.
  • Additionally, ACS Technology® can extend food products' value by aiding in making the food more nutritious through calcium enrichment.  Calcium enrichment is in demand and unlike most calcium in food today, the body absorbs calcium more easily, a true competitive advantage.
  • FDA and USDA Permitted as a Food Additive.

The ACS Technology's SAFE-phix® brand Family of Solutions is a unique broad based proprietary technology with a number of features that benefit a wide variety of industries.

Poultry drinking water, Freshflo or FreshFlo 100 chicken water treatment and drinking water processing is made with ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, for the   poultry industry.  Poultry water treatment with Acidic Calcium Sulfate, ACS 100, FreshFlo or FreshFlo 100 is a food grade acid to adjust food pH, and is primarily applied in the chicken industry for poultry water or chicken water.  The FreshFlo or FreshFlo 100 additive will make the water pure for animal drinking water.

The FreshFlo or FreshFlo 100 made with ACS Technology Inc. Safephix brand Acidic Calcium Sulfate, ACS 100 for animal drinking water can also control salmonella listeria in the water supply system and insures safe well water.  No fear of contamination of water for Acidic Calcium Sulfate, FreshFlo 10, nor pollution of groundwater.

This Acidic Calcium Sulfate, ACS 100, FreshFlo or FreshFlo 100 is also a Poultry nipple drinking line cleaner for safe drinking of poultry water in poultry drinkers that provide automatic chicken water in their chicken watering system.

ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, FreshFlo or FreshFlo 100 is a acidifier for chicken feed, chicken litter, broiler chicken production and in cattle feed additives.

In poultry processing plants, Acidic Calcium Sulfate, ACS 100, A pHixr or phixr 100 is utilized to optimize ORP Oxidation Reduction Potential in chlorinated water processing and maximizing bacterial killing effect.  This produces optimum hypoclorous acid for salmonellosis treatment or bacteria salmonella treatment.

In the food manufacturing and processing industry, ACS TechnologySafepHix brand Acidic Calcium Sulfate, ACS 100 or ACS, is a food agent used as an acidulant or pH adjustment chemicals for Kosher food production.  This application is primarily about food safety.  Depending of application, you may insert on list of food ingredients and on food ingredient labels.

pH adjustment chemicals can be used with ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, pHixr or pHixr 100 for ORP and pH adjustment, and in automatic pH adjuster, such as electronic monitoring pH indicator and dispensing equipment for adjusting pH in water, primarily to lower pH in water. Due to organic matter  (poultry) entering the poultry water or chicken water pushing the pH up, adding Acidic Calcium Sulfate, ACS 100, pHixr or pHixr 100 will increase the ORP of the poultry water processing  in poultry processing plants, optimizing the orp-oxidation reduction potential.

Food processing plants can also benefit in other applications when utilizing Acidic Calcium Sulfate, ACS 100,pHixr or pHixr 100 in their poultry processing water.  The ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, pHixr or pHixr 100 will begin controlling bacterial in floor drains with the food processing plants, as well as throughout the food processing equipment during the food process.  Within the food industry and the making of processed foods, food safety and Listeria salmonella prevention is of a particular concern.  New food processing technology and food processing methods, such as implementing Ready To Eat RTE 01 or rt-01, aka Acidic Calcium Sulfate, ACS 100, pHixr or pHixr 100 on or in the food processes or in lieu of any irradiated food is excellent for listeria salmonella prevention.

Acidic Calcium Sulfate, ACS 100, (aka Acidified Calcium Sulfate), can also be utilized in other pH adjustment systems, such as a  pH reducer or pH decreaser of the hydroponic pH in a hydroponic solution to help keep the ph down.

Pet food manufacturers also use ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, (aka Acidified Calcium Sulfate) as a pet food acidulant and to manufacturer pet products and pet feed.  This listeria salmonella and food borne illnesses prevention is desired by the feed manufacturer as well as pet products suppliers.

Food microbiology has shown that good food hygiene and food safe temperatures along with use of Acidic Calcium Sulfate, ACS 100, will control Salmonella Listeria, diseases in food and other hazards in food.  This has proven beneficial for controlling Salmonella and Campylobacter with use of ACS Technology SafepHix brand Acidic Calcium Sulfate, FreshFlo or FreshFlo 100, for antimicrobial effectiveness vegetable wash and vegetable cleaner on whole vegetables.  Also used for fruit wash.

Food industry leaders implement a food protection program using ACS Technology SafepHix brand ACS 100, acidic calcium sulfate, to insure quality control of food and any disease of bacteria.  Safety in the food industry is paramount for food quality management and quality control of meat and poultry.  Preventing bacterial food contamination, bacteria food poisoning or foodborne illnesses, such a campylobacter, Listeria m or salmonella food illness is essential food safety in food industry.

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ACS-Acidified Calcium Sulfate

 

MATERIAL SAFETY DATA SHEET

 

Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION

 

PRODUCT NAME      ACS-Acidified Calcium Sulfate                EMERGENCY NUMBER             800-424-9300         

3

HEALTH

HAZARD RATING

 

4=EXTREME

3=HIGH

2=MODERATE

1=SLIGHT

0=INSIGNIFICANT

0

FIRE

2

REACTIVITY

C

MINIMUM PERSONAL PROTECTION

A=GOGGLES  B=GOGGLES & GLOVES

C=GOGGLES, GLOVES, & APRON

 

MSDS NUMBER       14033                      PRODUCT USE                         Acidulant                

 

VERSION NUMBER   1.9                           DOT HAZARD CLASS                                8             

 

ISSUE DATE:            04/04/03                 DOT SHIPPING NAME:             Corrosive liquid, Acidic,

                                                                                                                Inorganic, N.O.S.

 

REVISION DATE:       09/09/07                 UN NUMBER                            3264

 

PREPARED BY:        ACS Technology       PACKAGING GROUP                                II

 

MANUFACTURER     Hydrite Chemical Co. for

ACS Technology

                                5470 Wilson Rd.

                                COS, CO 8099

                                719-265-9141

 

ABBREVIATION KEY: NA= Not Applicable   NE = Not Established   ND = Not Determined

Section 2 – HAZARDOUS INGREDIENTS INFORMATION

 

CHEMICAL INDENTITY                                    HAZARDOUS                                      CAS REG#                                    PERCENTAGES

 

Acidified Calcium Sulfate                                    Yes                                                   NA                                                20 – 30

 

Water                                                                    No                                              7732-18-5                                          70 – 80

 

 

Section 3 – PHYSICAL DATA

 

BOILING POINT: – 104ºC – 105ºC                        SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 10 - 1.13           ODOR: – Odorless and slightly acidic

 

PHYSICAL STATE: - Liquid                                   Appearance – clear to slightly cloudy or opaque       pH: - <1.0

 

FREEZING POINT:  - 5ºC

 

Section 4 – HEALTH HAZARD DATA

 

Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal.  Harmful if undiluted ACS-Acidified Calcium Sulfate inhaled.  Excessive heat (>100OC)  may cause volatility.  Slightly water reactive.  Contains strong inorganic acid.  Long term exposure to undiluted ACS-Acidified Calcium Sulfate may increase cancer risk. 

 

POTENTIAL HEALTH EFFECTS

 

Inhalation:  Inhalation of undiluted ACS-Acidified Calcium Sulfate may produces damaging effects  on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat.  May cause lung edema, a medical emergency.

 

Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted ACS-Acidified Calcium Sulfate.

 

Ingestion: ACS-Acidified Calcium Sulfate is a food additive, however ingestion of undiluted ACS Acidic Calcium Sulfate may cause burns to the mouth, throat, and stomach.

 

Eye Contact: Contact with undiluted ACS-Acidified Calcium Sulfate may cause blurred vision, redness, pain & severe tissue burns. 

 

Chronic Exposure: Chronic exposure to mist of the undiluted ACS-Acidified Calcium Sulfate may increase risk of cancer.

 

Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted ACS-Acidified Calcium Sulfate.

 

Section 5 – FIRST AID MEASURES

 

Inhalation:  Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

 

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.  Wash clothing before reuse.

 

Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

 

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

 

ACS TECHNOLOGY                                           Page I of 3         MSDS I4033 – ACS-ACIDIFIED CALCIUM SULFATE

 

Section 6 – FIRE FIGHTING MEASURES

 

Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10). 

 

Explosion: A mild exothermic reaction may occur  when undiluted ACS-Acidified Calcium Sulfate is added to water. 

Fire Extinguishing Media: Dry chemical, foam or carbon dioxide.  Water spray may be used to keep fire exposed containers cool.

 

Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.

 

Section 7 – ACCIDENTAL RELEASE MEASURES

 

 

Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. US regulations (CERCLA) require reporting spills and releases to soil, water, and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is 800-424-8802.

 

Section 8 – HANDLING AND STORAGE

 

Store  in well ventilated storage area.  Protect from physical damage. Keep  away from incompatible materials. When diluting, always add ACS Acidic Calcium Sulfate to water; never add water to undiluted ACS-Acidified Calcium Sulfate.  

 

Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Airborne Exposure Limits:

For  undiluted ACS-Acidified Calcium Sulfate.

-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)

-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL),  A2 - suspected human carcinogen for undiluted ACS-Acidified Calcium Sulfate contained in strong inorganic acid mists.

 

Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

 

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench

facilities in work area.

 

Section 10 – STABILITY AND REACTIVITY

 

Stability: Stable under ordinary conditions of use and storage.

 

Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

 

Hazardous Polymerization: Will not occur.

 

Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.

 

Conditions to Avoid:  Excessive Heat (>100OC) and incompatibles.

 

Section 11 – TOXICOLOGICAL INFORMATION

 

Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).

 

Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).

 

Section 12 – ECOLOGICAL INFORMATION

 

Environmental Fate: When released into the soil, this undiluted ACS-Acidified Calcium Sulfate may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.

Environmental Toxicity: This undiluted ACS-Acidified Calcium Sulfate may be toxic to aquatic life.

 

Section 13 – DISPOSAL CONSIDERATIONS

 

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

 

ACS TECHNOLOGY                                           Page 2 of 3           MSDS I4033 – ACS-ACIDIFIED CALCIUM SULFATE

 

 

Section 14 – TRANSPORTATION

 

Shipping Name:                      Corrosive liquid, Acidic, Inorganic, N.O.S (ACS-Acidified Calcium Sulfate)

Hazard Class:                          8

UN Number:                            UN3264

Packing Group:                      II

 

Section 15 – REGULATORY INFORMATION

 

TSCA

CAS# 7664-93-9 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

 

SARA

Section 313

ACS-Acidified Calcium Sulfate may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 7664-93-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, and Massachusetts.

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols:

C

 

Section 16 – ADDITIONAL INFORMATION

 

MSDS Creation Date: 6/20/2005

Revision #3 Date: 6/20/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

ACS TECHNOLOGY                                              Page 3 of 3                 MSDS I4033 – ACS-ACIDIFIED CALCIUM SULFATE

 

ACS-Acidic Calcium Sulfate

 

MATERIAL SAFETY DATA SHEET

 

Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION

 

PRODUCT NAME      ACS-Acidic Calcium Sulfate    EMERGENCY NUMBER             800-424-9300         

3

HEALTH

HAZARD RATING

 

4=EXTREME

3=HIGH

2=MODERATE

1=SLIGHT

0=INSIGNIFICANT

0

FIRE

2

REACTIVITY

C

MINIMUM PERSONAL PROTECTION

A=GOGGLES  B=GOGGLES & GLOVES

C=GOGGLES, GLOVES, & APRON

 

MSDS NUMBER       14033                      PRODUCT USE                         Acidulant                

 

VERSION NUMBER   1.9                           DOT HAZARD CLASS                                8             

 

ISSUE DATE:            04/04/03                 DOT SHIPPING NAME:             Corrosive liquid, Acidic,

                                                                                                                Inorganic, N.O.S.

 

REVISION DATE:       09/09/07                 UN NUMBER                            3264

 

PREPARED BY:        ACS Technology       PACKAGING GROUP                                II

 

MANUFACTURER     Hydrite Chemical Co. for

ACS Technology

                                5470 Wilson Rd.

                                COS, CO 8099

                                719-265-9141

 

ABBREVIATION KEY: NA= Not Applicable   NE = Not Established   ND = Not Determined

Section 2 – HAZARDOUS INGREDIENTS INFORMATION

 

CHEMICAL INDENTITY                                    HAZARDOUS                                      CAS REG#                                    PERCENTAGES

 

Acidic Calcium Sulfate                                         Yes                                                   NA                                                20 – 30

 

Water                                                                    No                                              7732-18-5                                          70 – 80

 

 

Section 3 – PHYSICAL DATA

 

BOILING POINT: – 104ºC – 105ºC                        SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 10 - 1.13           ODOR: – Odorless and slightly acidic

 

PHYSICAL STATE: - Liquid                                   Appearance – clear to slightly cloudy or opaque       pH: - <1.0

 

FREEZING POINT:  - 5ºC

 

Section 4 – HEALTH HAZARD DATA

 

Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal.  Harmful if undiluted ACS Acidic Calcium Sulfate inhaled.  Excessive heat (>100OC)  may cause volatility.  Slightly water reactive.  Contains strong inorganic acid.  Long term exposure to undiluted Acidic Calcium Sulfate may increase cancer risk. 

 

POTENTIAL HEALTH EFFECTS

 

Inhalation:  Inhalation of undiluted ACS Acidic Calcium Sulfate may produces damaging effects  on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat.  May cause lung edema, a medical emergency.

 

Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted ACS Acidic Calcium Sulfate.

 

Ingestion: ACS Acidic Calcium Sulfate is a food additive, however ingestion of undiluted ACS Acidic Calcium Sulfate may cause burns to the mouth, throat, and stomach.

 

Eye Contact: Contact with undiluted Acidic Calcium Sulfate may cause blurred vision, redness, pain & severe tissue burns. 

 

Chronic Exposure: Chronic exposure to mist of the undiluted ACS Acidic Calcium Sulfate may increase risk of cancer.

 

Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted ACS Acidic Calcium Sulfate.

 

Section 5 – FIRST AID MEASURES

 

Inhalation:  Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

 

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.  Wash clothing before reuse.

 

Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

 

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

 

 

ACS TECHNOLOGY                                                       Page I of 3         MSDS I4033 – ACS-ACIDIC CALCIUM SULFATE

 

Section 6 – FIRE FIGHTING MEASURES

 

Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10). 

 

Explosion: A mild exothermic reaction may occur  when undiluted ACS Acidic Calcium Sulfate is added to water. 

Fire Extinguishing Media: Dry chemical, foam or carbon dioxide.  Water spray may be used to keep fire exposed containers cool.

 

Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.

 

Section 7 – ACCIDENTAL RELEASE MEASURES

 

 

Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. US regulations (CERCLA) require reporting spills and releases to soil, water, and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is 800-424-8802.

 

Section 8 – HANDLING AND STORAGE

 

Store  in well ventilated storage area.  Protect from physical damage. Keep  away from incompatible materials. When diluting, always add ACS Acidic Calcium Sulfate to water; never add water to undiluted ACS Acidic Calcium Sulfate.  

 

Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Airborne Exposure Limits:

For  undiluted ACS Acidic Calcium Sulfate.

-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)

-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL),  A2 - suspected human carcinogen for undiluted ACS Acidic Calcium Sulfate contained in strong inorganic acid mists.

 

Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

 

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench

facilities in work area.

 

Section 10 – STABILITY AND REACTIVITY

 

Stability: Stable under ordinary conditions of use and storage.

 

Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

 

Hazardous Polymerization: Will not occur.

 

Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.

 

Conditions to Avoid:  Excessive Heat (>100OC) and incompatibles.

 

Section 11 – TOXICOLOGICAL INFORMATION

 

Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).

 

Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).

 

Section 12 – ECOLOGICAL INFORMATION

 

Environmental Fate: When released into the soil, this undiluted ACS Acidic Calcium Sulfate may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.

Environmental Toxicity: This undiluted ACS Acidic Calcium Sulfate may be toxic to aquatic life.

 

Section 13 – DISPOSAL CONSIDERATIONS

 

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

 

ACS TECHNOLOGY                                                       Page 2 of 3           MSDS I4033 – ACS-ACIDIC CALCIUM SULFATE

 

 

Section 14 – TRANSPORTATION

 

Shipping Name:                      Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)

Hazard Class:                          8

UN Number:                            UN3264

Packing Group:                      II

 

Section 15 – REGULATORY INFORMATION

 

TSCA

CAS# 7664-93-9 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

 

SARA

Section 313

ACS Acidic Calcium Sulfate may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 7664-93-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, and Massachusetts.

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols:

C

 

Section 16 – ADDITIONAL INFORMATION

 

MSDS Creation Date: 6/20/2005

Revision #3 Date: 6/20/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

ACS TECHNOLOGY                                                       Page 3 of 3                 MSDS I4033 – ACS-ACIDIC CALCIUM SULFATE

 

 

 ACS Technology, About Us, FreshFlo, pHixr, FDA, AFT, RTE, FSIS,Studies, Patents, Contact Info, Salmonella Treatment, PWT Poultry Water Treatment, pH water treatment,Deck cleaners, acidified calcium sulfate, acidic calcium sulfate, ACS 100, Pathogen Control, Animal Poultry Drinking Water, PWT Processing Water Treatment, Product Recalls,  RTE 01 Ready To Eat RTE Meats, Poultry Litter Treatment, ACS, FreshFlo FreshFlo100 MSDS, ACSTechnolgy.info, Poultry Nipple Drinker Line Cleaner,

MATERIAL SAFETY DATA SHEET

ACS 100 /Acidic Calcium Sulfate

Kosher Food Additive/Ingredient Acidifier

 

Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION

 

PRODUCT NAME      ACS 100 - Acidic Calcium Sulfate                                           EMERGENCY NUMBER   800-424-9300   

3

HEALTH

HAZARD RATING

 

4=EXTREME

3=HIGH

2=MODERATE

1=SLIGHT

0=INSIGNIFICANT

0

FIRE

2

REACTIVITY

C

MINIMUM PERSONAL PROTECTION

A=GOGGLES  B=GOGGLES & GLOVES

C=GOGGLES, GLOVES, & APRON

 

MSDS NUMBER       14033                      PRODUCT USE                         Acidulant                

 

VERSION NUMBER   1.9                           DOT HAZARD CLASS                                8             

 

ISSUE DATE:            04/04/03                 DOT SHIPPING NAME:             Corrosive liquid, Acidic,

                                                                                                                Inorganic, N.O.S.

 

REVISION DATE:       09/09/07                 UN NUMBER                            3264

 

PREPARED BY:        ACS Technology       PACKAGING GROUP                                II

 

MANUFACTURER     Hydrite Chemical Co. for

ACS Technology

                                5470 Wilson Rd.

                                COS, CO 8099

                                719-265-9141

 

 

ABBREVIATION KEY: NA= Not Applicable   NE = Not Established   ND = Not Determined

Section 2 – HAZARDOUS INGREDIENTS INFORMATION

 

 

CHEMICAL INDENTITY                                    HAZARDOUS                                      CAS REG#                                    PERCENTAGES

 

Acidic Calcium Sulfate                                         Yes                                                   NA                                                40 – 60

 

Water                                                                    No                                              7732-18-5                                          40 – 60

 

 

Section 3 – PHYSICAL DATA

 

BOILING POINT: – 104ºC – 105ºC                        SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 10 - 1.13           ODOR: – Odorless and slightly acidic

 

PHYSICAL STATE: - Liquid                                   Appearance – clear to slightly cloudy or opaque       pH: - <1.0

 

FREEZING POINT:  - 5ºC

 

Section 4 – HEALTH HAZARD DATA

 

Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal.  Harmful if undiluted Acidic Calcium Sulfate is inhaled.  Excessive heat (>100OC)  may cause volatility.  Slightly water reactive.  Contains strong inorganic acid. 

POTENTIAL HEALTH EFFECTS

 

Inhalation:  Inhalation of undiluted Acidic Calcium Sulfate may produces damaging effects  on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat.  May cause lung edema, a medical emergency.

 

Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted Acidic Calcium Sulfate.

 

Ingestion: Acidic Calcium Sulfate is a food additive, however ingestion of undiluted ACS 100 may  cause burns to the mouth, throat, and stomach.

 

Eye Contact: Contact with undiluted redness,  may cause blurred vision, and  pain & severe tissue burns.

 

Chronic Exposure: Chronic exposure to mist of the undiluted Acidic Calcium Sulfate may increase risk of cancer.

 

Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted Acidic Calcium Sulfate.

 

Section 5 – FIRST AID MEASURES

 

Inhalation:  Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

 

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.  Wash clothing before reuse.

 

Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

 

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

 

 

 

ACS TECHNOLOGY                                                       Page 1 of 3          MSDS I4033 – ACS 100 Acidic Calcium Sulfate

 

Section 6 – FIRE FIGHTING MEASURES

 

Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10). 

 

Explosion: A mild exothermic reaction may occur  when undiluted Acidic Calcium Sulfate is added to water. 

 

Fire Extinguishing Media: Dry chemical, foam or carbon dioxide.  Water spray may be used to keep fire exposed containers cool.

 

Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.

 

Section 7 – ACCIDENTAL RELEASE MEASURES

 

 

Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. US regulations (CERCLA) require reporting spills and releases to soil, water, and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is 800-424-8802.

 

Section 8 – HANDLING AND STORAGE

 

Store  in well ventilated storage area.  Protect from physical damage. Keep  away from incompatible materials. When diluting, always add ACS I00 to water; never add water to undiluted Acidic Calcium Sulfate.  

 

Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Airborne Exposure Limits:

For  undiluted Acidic Calcium Sulfate/ACS 100

-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)

-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL),  A2 - suspected human carcinogen for undiluted Acidic Calcium Sulfate/ ACS 100 contained in strong inorganic acid mists.

 

Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

 

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench

facilities in work area.

 

Section 10 – STABILITY AND REACTIVITY

 

Stability: Stable under ordinary conditions of use and storage.

 

Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

 

Hazardous Polymerization: Will not occur.

 

Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.

 

Conditions to Avoid:  Excessive Heat (>100OC) and incompatibles.

 

Section 11 – TOXICOLOGICAL INFORMATION

 

Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).

 

Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).

 

Section 12 – ECOLOGICAL INFORMATION

 

Environmental Fate: When released into the soil, this undiluted ACS 100 / Acidic Calcium Sulfate may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.

Environmental Toxicity: This undiluted Acidic Calcium Sulfate may be toxic to aquatic life.

 

Section 13 – DISPOSAL CONSIDERATIONS

 

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

 

ACS TECHNOLOGY                                                       Page 2 of 3          MSDS I4033 – ACS 100 Acidic Calcium Sulfate

Section 14 – TRANSPORTATION

 

Shipping Name:                      Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)

Hazard Class:                          8

UN Number:                            UN3264

Packing Group:                      II

 

Section 15 – REGULATORY INFORMATION

 

TSCA

CAS# 7664-93-9 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

 

SARA

Section 313

Acidic Calcium Sulfate may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 7664-93-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, and Massachusetts.

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols: C

 

Section 16 – ADDITIONAL INFORMATION

 

MSDS Creation Date: 6/20/2005

Revision #4 Date: 11/16/2011

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

ACS TECHNOLOGY                                                       Page 3 of                 MSDS I4033 – ACS 100 / Acidic Calcium Sulfate

MATERIAL SAFETY DATA SHEET

ACS 100 /Acidic Calcium Sulfate

Kosher Food Additive/Ingredient Acidifier

 

Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION

 

PRODUCT NAME      ACS 100 - Acidic Calcium Sulfate                                           EMERGENCY NUMBER   800-424-9300   

3

HEALTH

HAZARD RATING

 

4=EXTREME

3=HIGH

2=MODERATE

1=SLIGHT

0=INSIGNIFICANT

0

FIRE

2

REACTIVITY

C

MINIMUM PERSONAL PROTECTION

A=GOGGLES  B=GOGGLES & GLOVES

C=GOGGLES, GLOVES, & APRON

 

MSDS NUMBER       14033                      PRODUCT USE                         Acidulant                

 

VERSION NUMBER   1.9                           DOT HAZARD CLASS                                8             

 

ISSUE DATE:            04/04/03                 DOT SHIPPING NAME:             Corrosive liquid, Acidic,

                                                                                                                Inorganic, N.O.S.

 

REVISION DATE:       09/09/07                 UN NUMBER                            3264

 

PREPARED BY:        ACS Technology       PACKAGING GROUP                                II

 

MANUFACTURER     Hydrite Chemical Co. for

ACS Technology

                                5470 Wilson Rd.

                                COS, CO 8099

                                719-265-9141

 

 

ABBREVIATION KEY: NA= Not Applicable   NE = Not Established   ND = Not Determined

Section 2 – HAZARDOUS INGREDIENTS INFORMATION

 

 

CHEMICAL INDENTITY                                    HAZARDOUS                                      CAS REG#                                    PERCENTAGES

 

Acidic Calcium Sulfate                                         Yes                                                   NA                                                40 – 60

 

Water                                                                    No                                              7732-18-5                                          40 – 60

 

 

Section 3 – PHYSICAL DATA

 

BOILING POINT: – 104ºC – 105ºC                        SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 10 - 1.13           ODOR: – Odorless and slightly acidic

 

PHYSICAL STATE: - Liquid                                   Appearance – clear to slightly cloudy or opaque       pH: - <1.0

 

FREEZING POINT:  - 5ºC

 

Section 4 – HEALTH HAZARD DATA

 

Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal.  Harmful if undiluted Acidic Calcium Sulfate is inhaled.  Excessive heat (>100OC)  may cause volatility.  Slightly water reactive.  Contains strong inorganic acid. 

POTENTIAL HEALTH EFFECTS

 

Inhalation:  Inhalation of undiluted Acidic Calcium Sulfate may produces damaging effects  on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat.  May cause lung edema, a medical emergency.

 

Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted Acidic Calcium Sulfate.

 

Ingestion: Acidic Calcium Sulfate is a food additive, however ingestion of undiluted ACS 100 may  cause burns to the mouth, throat, and stomach.

Eye Contact: Contact with undiluted redness,  may cause blurred vision, and  pain & severe tissue burns.

 

Chronic Exposure: Chronic exposure to mist of the undiluted Acidic Calcium Sulfate may increase risk of cancer.

 

Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted Acidic Calcium Sulfate.

 

Section 5 – FIRST AID MEASURES

 

Inhalation:  Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

 

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.  Wash clothing before reuse.

 

Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

 

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

 

 

 

ACS TECHNOLOGY                                                       Page 1 of 3          MSDS I4033 – ACS 100 Acidic Calcium Sulfate

 

Section 6 – FIRE FIGHTING MEASURES

 

Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10). 

 

Explosion: A mild exothermic reaction may occur  when undiluted Acidic Calcium Sulfate is added to water. 

Fire Extinguishing Media: Dry chemical, foam or carbon dioxide.  Water spray may be used to keep fire exposed containers cool.

 

Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.

 

Section 7 – ACCIDENTAL RELEASE MEASURES

 

 

Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. US regulations (CERCLA) require reporting spills and releases to soil, water, and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is 800-424-8802.

 

Section 8 – HANDLING AND STORAGE

 

Store  in well ventilated storage area.  Protect from physical damage. Keep  away from incompatible materials. When diluting, always add ACS I00 to water; never add water to undiluted Acidic Calcium Sulfate.  

 

Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Airborne Exposure Limits:

For  undiluted Acidic Calcium Sulfate/ACS 100

-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)

-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL),  A2 - suspected human carcinogen for undiluted Acidic Calcium Sulfate/ ACS 100 contained in strong inorganic acid mists.

 

Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

 

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench

facilities in work area.

 

Section 10 – STABILITY AND REACTIVITY

 

Stability: Stable under ordinary conditions of use and storage.

 

Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

 

Hazardous Polymerization: Will not occur.

 

Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.

 

Conditions to Avoid:  Excessive Heat (>100OC) and incompatibles.

 

Section 11 – TOXICOLOGICAL INFORMATION

 

Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).

 

Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).

 

Section 12 – ECOLOGICAL INFORMATION

 

Environmental Fate: When released into the soil, this undiluted ACS 100 / Acidic Calcium Sulfate may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.

Environmental Toxicity: This undiluted Acidic Calcium Sulfate may be toxic to aquatic life.

 

Section 13 – DISPOSAL CONSIDERATIONS

 

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

 

ACS TECHNOLOGY                                                       Page 2 of 3          MSDS I4033 – ACS 100 Acidic Calcium Sulfate

Section 14 – TRANSPORTATION

 

Shipping Name:                      Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)

Hazard Class:                          8

UN Number:                            UN3264

Packing Group:                      II

Section 15 – REGULATORY INFORMATION

 

TSCA

CAS# 7664-93-9 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

 

SARA

Section 313

Acidic Calcium Sulfate may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 7664-93-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, and Massachusetts.

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols: C

 

Section 16 – ADDITIONAL INFORMATION

 

MSDS Creation Date: 6/20/2005

Revision #4 Date: 11/16/2011

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

ACS TECHNOLOGY                                                       Page 3 of                 MSDS I4033 – ACS 100 / Acidic Calcium Sulfate

 

 

 

 

 

 

 

 

 

 

 








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The ACS Technology's SAFE-phix® brand Family of Solutions is a unique broad based proprietary technology with a number of features that benefit a wide variety of industries.
 

MATERIAL SAFETY DATA SHEET

ACS 100 /Acidic Calcium Sulfate

Kosher Food Additive/Ingredient Acidifier

 

Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION

 

PRODUCT NAME      ACS 100 - Acidic Calcium Sulfate                                           EMERGENCY NUMBER   800-424-9300   

3

HEALTH

HAZARD RATING

 

4=EXTREME

3=HIGH

2=MODERATE

1=SLIGHT

0=INSIGNIFICANT

0

FIRE

2

REACTIVITY

C

MINIMUM PERSONAL PROTECTION

A=GOGGLES  B=GOGGLES & GLOVES

C=GOGGLES, GLOVES, & APRON

 

MSDS NUMBER       14033                      PRODUCT USE                         Acidulant                

 

VERSION NUMBER   1.9                           DOT HAZARD CLASS                                8             

 

ISSUE DATE:            04/04/03                 DOT SHIPPING NAME:             Corrosive liquid, Acidic,

                                                                                                                Inorganic, N.O.S.

 

REVISION DATE:       09/09/07                 UN NUMBER                            3264

 

PREPARED BY:        ACS Technology       PACKAGING GROUP                                II

 

MANUFACTURER     Hydrite Chemical Co. for

ACS Technology

                                5470 Wilson Rd.

                                COS, CO 8099

                                719-265-9141

 

 

ABBREVIATION KEY: NA= Not Applicable   NE = Not Established   ND = Not Determined

Section 2 – HAZARDOUS INGREDIENTS INFORMATION

 

 

CHEMICAL INDENTITY                                    HAZARDOUS                                      CAS REG#                                    PERCENTAGES

 

Acidic Calcium Sulfate                                         Yes                                                   NA                                                40 – 60

 

Water                                                                    No                                              7732-18-5                                          40 – 60

 

 

Section 3 – PHYSICAL DATA

 

BOILING POINT: – 104ºC – 105ºC                        SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 10 - 1.13           ODOR: – Odorless and slightly acidic

 

PHYSICAL STATE: - Liquid                                   Appearance – clear to slightly cloudy or opaque       pH: - <1.0

 

FREEZING POINT:  - 5ºC

 

Section 4 – HEALTH HAZARD DATA

 

Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal.  Harmful if undiluted Acidic Calcium Sulfate is inhaled.  Excessive heat (>100OC)  may cause volatility.  Slightly water reactive.  Contains strong inorganic acid. 

POTENTIAL HEALTH EFFECTS

 

Inhalation:  Inhalation of undiluted Acidic Calcium Sulfate may produces damaging effects  on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat.  May cause lung edema, a medical emergency.

 

Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted Acidic Calcium Sulfate.

 

Ingestion: Acidic Calcium Sulfate is a food additive, however ingestion of undiluted ACS 100 may  cause burns to the mouth, throat, and stomach.

 

Eye Contact: Contact with undiluted redness,  may cause blurred vision, and  pain & severe tissue burns.

 

Chronic Exposure: Chronic exposure to mist of the undiluted Acidic Calcium Sulfate may increase risk of cancer.

 

Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted Acidic Calcium Sulfate.

 

Section 5 – FIRST AID MEASURES

 

Inhalation:  Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.

 

Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.  Wash clothing before reuse.

 

Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.

 

Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

 

 

 

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Section 6 – FIRE FIGHTING MEASURES

 

Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10). 

 

Explosion: A mild exothermic reaction may occur  when undiluted Acidic Calcium Sulfate is added to water. 

 

Fire Extinguishing Media: Dry chemical, foam or carbon dioxide.  Water spray may be used to keep fire exposed containers cool.

 

Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.

 

Section 7 – ACCIDENTAL RELEASE MEASURES

 

 

Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer. US regulations (CERCLA) require reporting spills and releases to soil, water, and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is 800-424-8802.

 

Section 8 – HANDLING AND STORAGE

 

Store  in well ventilated storage area.  Protect from physical damage. Keep  away from incompatible materials. When diluting, always add ACS I00 to water; never add water to undiluted Acidic Calcium Sulfate.  

 

Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION

 

Airborne Exposure Limits:

For  undiluted Acidic Calcium Sulfate/ACS 100

-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)

-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL),  A2 - suspected human carcinogen for undiluted Acidic Calcium Sulfate/ ACS 100 contained in strong inorganic acid mists.

 

Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

 

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench

facilities in work area.

 

Section 10 – STABILITY AND REACTIVITY

 

Stability: Stable under ordinary conditions of use and storage.

 

Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

 

Hazardous Polymerization: Will not occur.

 

Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.

 

Conditions to Avoid:  Excessive Heat (>100OC) and incompatibles.

 

Section 11 – TOXICOLOGICAL INFORMATION

 

Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).

 

Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).

 

Section 12 – ECOLOGICAL INFORMATION

 

Environmental Fate: When released into the soil, this undiluted ACS 100 / Acidic Calcium Sulfate may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.

Environmental Toxicity: This undiluted Acidic Calcium Sulfate may be toxic to aquatic life.

 

Section 13 – DISPOSAL CONSIDERATIONS

 

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed.

 

ACS TECHNOLOGY                                                       Page 2 of 3          MSDS I4033 – ACS 100 Acidic Calcium Sulfate

Section 14 – TRANSPORTATION

 

Shipping Name:                      Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)

Hazard Class:                          8

UN Number:                            UN3264

Packing Group:                      II

 

Section 15 – REGULATORY INFORMATION

 

TSCA

CAS# 7664-93-9 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

 

SARA

Section 313

Acidic Calcium Sulfate may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.

Clean Air Act:

This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 7664-93-9 can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, and Massachusetts.

California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols: C

 

Section 16 – ADDITIONAL INFORMATION

 

MSDS Creation Date: 6/20/2005

Revision #4 Date: 11/16/2011

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

ACS TECHNOLOGY                                                       Page 3 of                 MSDS I4033 – ACS 100 / Acidic Calcium Sulfate

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