ACS Technology
Providing
Pathogen Control and
Extend Shelf-Life
with
"ACS"
Acidic Calcium Sulfate
" USDA & FDA Approved "
FreshFlo 100 - Poultry Waterer Drinking Treatment / PWT Liquid
FDA & USDA approved
Human food grade inorganic acid water treatment available to the poultry industry
What Is FreshFlo 100®
- Poultry/Chicken drinking water acidulant to safely and effectively lower pH levels for achieving optimum health benefits and to reduce mortality rate and provide maximum yield.
- No bitter taste issues for birds, to insure optimum water consumption
- Applied effectively with broilers, pullets and broiler breeders, commercial turkeys & breeders, commercial egg layers.
- Manufactured from FCC grade raw materials that are (GRAS) Generally Recognized As Safe
by the FDA. - USDA Approved
- Patented Technology
- A proprietary blend of inorganic materials having the properties of an organic acid.
Click here to Contact Us to order or for further information and pricing
ADVANTAGES & BENEFITS of FreshFlo 100®
- Adjusts animal drinking water pH.
- No bitter off-taste so the treated water is readily consumed.
- Ready-to-use and can be metered directly into water lines.
- Ease of use minimizes labor, mixing errors and spillage.
- Safe Handling & Fit for human consumption. No fear of contamination to well water.
MONEY SAVING FEATURES of FreshFlo 100®
- FreshFlo® optimizes animal drinking water by reducing water pH* and increasing functionality of chlorination. (Optimizes ORP-Oxidation Reduction Potential to insure maxium hypoclorous acid {Bacteria Killer} of your chlorinated drinking water)
- University studies have shown a reduced mortality rate at lowered water pH.
*Amount of FreshFlo required to adjust water pH may vary by
location depending upon water quality (pH and dissolved
chemicals such as minerals, bicarbonates, etc.)
FreshFlo 100®, our premium poultry drinking water acidulant is focused on providing food animal growers with a reduction and control of bacterial contaminates, reducing mortality rates and improving yields.
The ACS Technology's SAFE-phix® brand Family of Solutions is a unique broad based proprietary technology with a number of features that benefit a wide variety of industries. Poultry drinking water, Freshflo or FreshFlo 100 chicken water treatment and drinking water processing is made with ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, for the poultry industry. Poultry water treatment with Acidic Calcium Sulfate, ACS 100, FreshFlo or FreshFlo 100 is a food grade acid to adjust food pH, and is primarily applied in the chicken industry for poultry water or chicken water. The FreshFlo or FreshFlo 100 additive will make the water pure for animal drinking water. The FreshFlo or FreshFlo 100 made with ACS Technology Inc. Safephix brand Acidic Calcium Sulfate, ACS 100 for animal drinking water can also control salmonella listeria in the water supply system and insures safe well water. No fear of contamination of water for Acidic Calcium Sulfate, FreshFlo 10, nor pollution of groundwater. This Acidic Calcium Sulfate, ACS 100, FreshFlo or FreshFlo 100 is also a Poultry nipple drinking line cleaner for safe drinking of poultry water in poultry drinkers that provide automatic chicken water in their chicken watering system. ACS Technology SafepHix brand Acidic Calcium Sulfate, ACS 100, FreshFlo or FreshFlo 100 is a acidifier for chicken feed, chicken litter, broiler chicken production and in cattle feed additives. For further information
Click on our other page buttons
or call 719-265-9141
or e-mail to
Applications@ACSProductInfo.com please contact us for a PDF file MSDS or call MATERIAL SAFETY DATA SHEET Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION PRODUCT NAME FreshFlo I00 Poultry Water Treatment EMERGENCY NUMBER 800-424-9300
3 HEALTH HAZARD RATING 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT 0 FIRE 2 REACTIVITY C MINIMUM PERSONAL PROTECTION A=GOGGLES B=GOGGLES & GLOVES C=GOGGLES, GLOVES, & APRON
719-265-9141
FreshFlo 100 Poultry Water Treatment
MSDS NUMBER 14076-H PRODUCT USE Acidulant
VERSION NUMBER 1.0 DOT HAZARD CLASS 8
ISSUE DATE: 09/04/07 DOT SHIPPING NAME: Corrosive liquid, Acidic,
Inorganic, N.O.S.
REVISION DATE: 09/09/07 UN NUMBER 3264
PREPARED BY: ACS Technology PACKAGING GROUP II
MANUFACTURER Hydrite Chemical Co for
ACS Technology
719-265-9141
ABBREVIATION KEY: NA= Not Applicable NE = Not Established ND = Not Determined
Section 2 – HAZARDOUS INGREDIENTS INFORMATION
CHEMICAL INDENTITY HAZARDOUS CAS REG# PERCENTAGES
Acidic Calcium Sulfate Yes NA 40 – 60
Water No 7732-18-5 40 – 60
Section 3 – PHYSICAL DATA
BOILING POINT: – 104ºC – 105ºC SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 28 - 1.30 ODOR: – Odorless and slightly acidic
FREEZING POINT: - 5ºC
Section 4 – HEALTH HAZARD DATA
Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal. Harmful if undiluted FreshFlo I00 Poultry Water Treatment is inhaled. Excessive heat (>100OC) may cause volatility. Slightly water reactive. Contains strong inorganic acid. Long term exposure to undiluted FreshFlo I00 Poultry Water Treatment may increase cancer risk.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of undiluted FreshFlo I00 Poultry Water Treatment may produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat. May cause lung edema, a medical emergency.
Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted FreshFlo I00 Poultry Water Treatment.
Ingestion: FreshFlo I00 Poultry Water Treatment is a food additive, however ingestion of undiluted FreshFlo I00 may cause burns to the mouth, throat, and stomach.
Eye Contact: Contact with undiluted FreshFlo I00 Poultry Water Treatment may cause blurred vision, redness, pain & severe tissue burns.
Chronic Exposure: Chronic exposure to mist of the undiluted FreshFlo I00 Poultry Water Treatment may increase risk of cancer.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted FreshFlo I00 Poultry Water Treatment.
Section 5 – FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
ACS TECHNOLOGY Page I of MSDS I4076-H – FreshFlo I00 Poultry Water Treatment
Section 6 – FIRE FIGHTING MEASURES
Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10).
Explosion: A mild exothermic reaction may occur when undiluted FreshFlo I00 Poultry Water Treatment is added to water.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.
Section 7 – ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer.
Section 8 – HANDLING AND STORAGE
Store in well ventilated storage area. Protect from physical damage. Keep away from incompatible materials. When diluting, always add FreshFlo I00 Poultry Water Treatment to water; never add water to undiluted FreshFlo I00 Poultry Water Treatment.
Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION
Airborne Exposure Limits:
For undiluted FreshFlo I00 Poultry Water Treatment.
-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)
-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL), A2 - suspected human carcinogen for undiluted FreshFlo I00 Poultry Water Treatment contained in strong inorganic acid mists.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Section 10 – STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization: Will not occur.
Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.
Conditions to Avoid: Excessive Heat (>100OC) and incompatibles.
Section 11 – TOXICOLOGICAL INFORMATION
Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).
Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).
Section 12 – ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this undiluted FreshFlo I00 Poultry Water Treatment may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity: This undiluted FreshFlo I00 Poultry Water Treatment may be toxic to aquatic life.
Section 13 – DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
ACS TECHNOLOGY Page 2 of 3 MSDS I4076-H – FreshFlo I00 Poultry Water Treatment
Section 14 – TRANSPORTATION
Shipping Name: Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)
Hazard Class: 8
UN Number: UN3264
Packing Group: II
Section 15 – REGULATORY INFORMATION
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 313
FreshFlo 100 Poultry Water Treatment may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Section 16 – ADDITIONAL INFORMATION
MSDS Creation Date: 6/20/2005
Revision #3 Date: 6/20/2006
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – FreshFlo I00 Poultry Water Treatment
FreshFlo 100 Poultry Nipple Drinker Line Cleaner
MATERIAL SAFETY DATA SHEET
Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION
PRODUCT NAME FreshFlo I00 Poultry Nipple Drinker Line Cleaner EMERGENCY NUMBER 800-424-9300
|
3 |
HEALTH |
HAZARD RATING 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT |
|
0 |
FIRE |
|
|
2 |
REACTIVITY |
|
|
C |
MINIMUM PERSONAL PROTECTION |
|
|
A=GOGGLES B=GOGGLES & GLOVES C=GOGGLES, GLOVES, & APRON |
||
MSDS NUMBER 14076-H PRODUCT USE Acidulant
VERSION NUMBER 1.0 DOT HAZARD CLASS 8
ISSUE DATE: 09/04/07 DOT SHIPPING NAME: Corrosive liquid, Acidic,
Inorganic, N.O.S.
REVISION DATE: 09/09/07 UN NUMBER 3264
PREPARED BY: ACS Technology PACKAGING GROUP II
MANUFACTURER Hydrite Chemical Co for
ACS Technology
719-265-9141
ABBREVIATION KEY: NA= Not Applicable NE = Not Established ND = Not Determined
Section 2 – HAZARDOUS INGREDIENTS INFORMATION
CHEMICAL INDENTITY HAZARDOUS CAS REG# PERCENTAGES
Acidic Calcium Sulfate Yes NA 40 – 60
Water No 7732-18-5 40 – 60
Section 3 – PHYSICAL DATA
BOILING POINT: – 104ºC – 105ºC SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 28 - 1.30 ODOR: – Odorless and slightly acidic
FREEZING POINT: - 5ºC
Section 4 – HEALTH HAZARD DATA
Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal. Harmful if undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner is inhaled. Excessive heat (>100OC) may cause volatility. Slightly water reactive. Contains strong inorganic acid.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner may produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat. May cause lung edema, a medical emergency.
Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner.
Ingestion: FreshFlo I00 Poultry Nipple Drinker Line Cleaner is a food additive, however ingestion of undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner may cause burns to the mouth, throat, and stomach.
Eye Contact: Contact with undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner may cause blurred vision, redness, pain & severe tissue burns.
Chronic Exposure: Chronic exposure to mist of the undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner may increase risk of cancer.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner.
Section 5 – FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
ACS TECHNOLOGY Page I of 3 MSDS I4076-H – FreshFlo I00 Poultry Nipple Drinker Line Cleaner
Section 6 – FIRE FIGHTING MEASURES
Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10).
Explosion: A mild exothermic reaction may occur when undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner is added to water.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.
Section 7 – ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer.
Section 8 – HANDLING AND STORAGE
Store in well ventilated storage area. Protect from physical damage. Keep away from incompatible materials. When diluting, always add FreshFlo I00 Poultry Nipple Drinker Line Cleaner to water; never add water to undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner.
Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION
Airborne Exposure Limits:
For undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner.
-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)
-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL), A2 - suspected human carcinogen for undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner contained in strong inorganic acid mists.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Section 10 – STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization: Will not occur.
Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.
Conditions to Avoid: Excessive Heat (>100OC) and incompatibles.
Section 11 – TOXICOLOGICAL INFORMATION
Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).
Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).
Section 12 – ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity: This undiluted FreshFlo I00 Poultry Nipple Drinker Line Cleaner may be toxic to aquatic life.
Section 13 – DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
ACS TECHNOLOGY Page 2 of 3 MSDS I4076-H – FreshFlo I00 Poultry Nipple Drinker Line Cleaner
Section 14 – TRANSPORTATION
Shipping Name: Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)
Hazard Class: 8
UN Number: UN3264
Packing Group: II
Section 15 – REGULATORY INFORMATION
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 313
FreshFlo I00 Poultry Nipple Drinker Line Cleaner may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Section 16 – ADDITIONAL INFORMATION
MSDS Creation Date: 6/20/2005
Revision #3 Date: 6/20/2006
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H –FreshFlo I00 Poultry Nipple Drinker Line Cleaner
Acidified Calcium Sulfate FreshFlo 100
MATERIAL SAFETY DATA SHEET
Section 1 – PRODUCT / MANUFACTURE’S IDENTIFICATION
PRODUCT NAME Acidified Calcium Sulfate FreshFlo I00 EMERGENCY NUMBER 800-424-9300
|
3 |
HEALTH |
HAZARD RATING 4=EXTREME 3=HIGH 2=MODERATE 1=SLIGHT 0=INSIGNIFICANT |
|
0 |
FIRE |
|
|
2 |
REACTIVITY |
|
|
C |
MINIMUM PERSONAL PROTECTION |
|
|
A=GOGGLES B=GOGGLES & GLOVES C=GOGGLES, GLOVES, & APRON |
||
MSDS NUMBER 14076-H PRODUCT USE Acidulant
VERSION NUMBER 1.0 DOT HAZARD CLASS 8
ISSUE DATE: 09/04/07 DOT SHIPPING NAME: Corrosive liquid, Acidic,
Inorganic, N.O.S.
REVISION DATE: 09/09/07 UN NUMBER 3264
PREPARED BY: ACS Technology PACKAGING GROUP II
MANUFACTURER Hydrite Chemical Co for
ACS Technology
719-265-9141
ABBREVIATION KEY: NA= Not Applicable NE = Not Established ND = Not Determined
Section 2 – HAZARDOUS INGREDIENTS INFORMATION
CHEMICAL INDENTITY HAZARDOUS CAS REG# PERCENTAGES
Acidic Calcium Sulfate Yes NA 40 – 60
Water No 7732-18-5 40 – 60
Section 3 – PHYSICAL DATA
BOILING POINT: – 104ºC – 105ºC SPECIFIC GRAVITY: – (H2O = 1.0) – 1. 28 - 1.30 ODOR: – Odorless and slightly acidic
FREEZING POINT: - 5ºC
Section 4 – HEALTH HAZARD DATA
Exposure to significant quantities of liquid and/or mist may cause irritation or burns to body tissue. Swallowing of large quantities may be fatal. Harmful if undiluted Acidified Calcium Sulfate FreshFlo I00 is inhaled. Excessive heat (>100OC) may cause volatility. Slightly water reactive. Contains strong inorganic acid. Long term exposure to undiluted Acidified Calcium Sulfate FreshFlo I00 may increase cancer risk.
POTENTIAL HEALTH EFFECTS
Inhalation: Inhalation of undiluted Acidified Calcium Sulfate FreshFlo I00 may produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat. May cause lung edema, a medical emergency.
Skin Contact: Corrosive. Symptoms of redness, pain, and burn can occur by skin contact with undiluted Acidified Calcium Sulfate FreshFlo I00.
Ingestion: FreshFlo I00 is a food additive, however ingestion of undiluted Acidified Calcium Sulfate FreshFlo I00 may cause burns to the mouth, throat, and stomach.
Eye Contact: Contact with undiluted Acidified Calcium Sulfate FreshFlo I00 may cause blurred vision, redness, pain & severe tissue burns.
Chronic Exposure: Chronic exposure to mist of the undiluted Acidified Calcium Sulfate FreshFlo I00 may increase risk of cancer.
Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of undiluted Acidified Calcium Sulfate FreshFlo I00.
Section 5 – FIRST AID MEASURES
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If swallowed, DO NOT INDUCE VOMITNG. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
ACS TECHNOLOGY Page I of 3 MSDS I4076-H – Acidified Calcium Sulfate FreshFlo I00
Section 6 – FIRE FIGHTING MEASURES
Fire: Concentrated material is a strong dehydrating agent. Do not store around unapproved chemicals (see Section 10).
Explosion: A mild exothermic reaction may occur when undiluted Acidified Calcium Sulfate FreshFlo I00 is added to water.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide. Water spray may be used to keep fire exposed containers cool.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. Structural firefighter's clothing is ineffective for fires involving this material. Stay away from sealed containers.
Section 7 – ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Wear appropriate personal protective equipment. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e.g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer.
Section 8 – HANDLING AND STORAGE
Store in well ventilated storage area. Protect from physical damage. Keep away from incompatible materials. When diluting, always add FreshFlo I00 to water; never add water to undiluted Acidified Calcium Sulfate FreshFlo I00.
Section 9 – EXPOSURE CONTROLS / PERSONAL PROTECTION
Airborne Exposure Limits:
For undiluted Acidified Calcium Sulfate FreshFlo I00.
-OSHA Permissible Exposure Unit (PEL): 1mg/m3 (TWA)
-ACGIH Threshold Unit Value (TLV): 1 mg/m3 (TWA), 3 mg/m3 (STEL), A2 - suspected human carcinogen for undiluted Acidic Calcium Sulfate FreshFlo I00 contained in strong inorganic acid mists.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Section 10 – STABILITY AND REACTIVITY
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Reacts with carbonates to generate carbon dioxide gas, and with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.
Hazardous Polymerization: Will not occur.
Incompatibilities: Potassium chlorate, potassium perchlorate, potassium permanganate, sodium, lithium, bases, organic material, halogens, metal acetyl ides, oxides and hydrides, metals (yields hydrogen gas), strong oxidizing and reducing agents and many other reactive substances.
Conditions to Avoid: Excessive Heat (>100OC) and incompatibles.
Section 11 – TOXICOLOGICAL INFORMATION
Toxicological Data: Oral rat LD50: 2140 mg/kg; inhalation rat LC50: 510 mg/m3/2H; standard Draize, eye rabbit, 250 µg (severe); investigated as a tumorigen, mutagen, reproductive effector (0.1N solution).
Carcinogenicity: Cancer Status: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists" as a known human carcinogen, (IARC category 1).
Section 12 – ECOLOGICAL INFORMATION
Environmental Fate: When released into the soil, this undiluted Acidified Calcium Sulfate FreshFlo I00 amay leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by wet deposition. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition.
Environmental Toxicity: This undiluted Acidified Calcium Sulfate FreshFlo I00 may be toxic to aquatic life.
Section 13 – DISPOSAL CONSIDERATIONS
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
ACS TECHNOLOGY Page 2 of 3 MSDS I4076-H – Acidified Calcium Sulfate FreshFlo I00
Section 14 – TRANSPORTATION
Shipping Name: Corrosive liquid, Acidic, Inorganic, N.O.S (ACIDIC CALCIUM SULFATE)
Hazard Class: 8
UN Number: UN3264
Packing Group: II
Section 15 – REGULATORY INFORMATION
TSCA
CAS# 7664-93-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
Section 313
Acidified Calcium Sulfate FreshFlo 100 may contain sulfuric acid (CAS# 7664-93-9, 95 98 0%), which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7664-93-9 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7664-93-9 can be found on the following state right to know lists:
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Section 16 – ADDITIONAL INFORMATION
MSDS Creation Date: 6/20/2005
Revision #3 Date: 6/20/2006
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ACS Technology be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ASC Technology has been advised of the possibility of such damages
ACS TECHNOLOGY Page 3 of 3 MSDS I4076-H – Acidified Calcium Sulfate FreshFlo I00
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